CMC Medical CMC-Medical Ludhiana Solved Paper-2015

  • question_answer
    The correct order of basic nature of the following compounds is
    (I) (II)
    (III) (IV)

    A)  \[I<II<III<IV\]  

    B)  \[IV<II<III<II\]

    C)  \[I<II<IV<III\]  

    D)  \[IV<III<I<II\]

    Correct Answer: A

    Solution :

                    Presence of electron donating groups like\[-OC{{H}_{3}}\] and \[-C{{H}_{3}}\]increase the basicity of amines whereas, presence of electron withdrawing. group like \[-N{{O}_{2}}\] decrease the basicity of amines, Hence, basicity increases in the order I < II < III < IV.


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