MGIMS WARDHA MGIMS WARDHA Solved Paper-2013

  • question_answer
    Which is not true statement?

    A)  Ions of d-block elements are coloured due to d-d transition

    B)  lons of\[f-\]block elements are coloured due to\[f-f\]transition

    C) \[{{[Sc{{({{H}_{2}}O)}_{6}}]}^{3+}},{{[Ti{{({{H}_{2}}O)}_{6}}]}^{4+}}\]are coloured complexes

    D)  \[C{{u}^{+}}\] is colourless ion

    Correct Answer: C

    Solution :

                    \[S{{c}^{3+}}(3{{d}^{0}})\]and\[T{{i}^{4+}}(3{{d}^{0}})\]are colourless because they have empty\[d-\]orbitals, hence \[d-d\]transition is impossible.


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