RAJASTHAN PMT Rajasthan - PMT Solved Paper-1997

  • question_answer
    The oxidation number of S in Marshal acid:

    A)  \[+6\]                                  

    B)                         \[+5\] 

    C)                         \[-7\]                                   

    D)                         \[+8\]

    Correct Answer: A

    Solution :

    \[{{H}_{2}}{{S}_{2}}{{O}_{8}}\](perdisulphuric acid or Marshal acid) \[H-O-\underset{O}{\mathop{\underset{||}{\mathop{\overset{O}{\mathop{\overset{||}{\mathop{S}}\,}}\,}}\,}}\,-\overset{-1}{\mathop{O}}\,-\overset{-1}{\mathop{O}}\,-\underset{O}{\mathop{\underset{||}{\mathop{\overset{O}{\mathop{\overset{||}{\mathop{S}}\,}}\,}}\,}}\,-O-H\] \[(+1\times 2)+2x+(-1\times 2)+(-2\times 6)=0\]                 \[2+2x-2-12=0\]                                 \[2x-12=0\]                                 \[x=6\]                                


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