Answer:
The reactivity in \[{{S}_{N}}1\] reactions depends upon the stability of the intermediate carbocation which an alkyl halide gives on ionization.
(i)
Since \[3{}^\circ \] carbocations are more stable than\[2{}^\circ \] carbocations, therefore, will react faster than
(ii)
Since \[2{}^\circ \] carbocations are more stable than \[1{}^\circ \]carbocations, therefore, reacts faster than .
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