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question_answer1) Directions: (Q. 1 to 15) For question numbers 1-15, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. Assertion: Compared to other noble gases, Xe is chemically reactive. Reason: Xe has low ionisation potential value.
question_answer2) Assertion: Both rhombic and monoclinic sulphur exist as \[{{S}_{8}}\] but oxygen exists as \[{{O}_{2}}\]. Reason: Oxygen forms \[p\pi -p\pi \]multiple bond due to small size and small bond length but \[p\pi -p\pi \] bonding is not possible in sulphur.
question_answer3) Assertion: Nitrogen has higher ionization energy than that of oxygen. Reason: Nitrogen has smaller atomic size than that of oxygen.
question_answer4) Assertion: Most of known noble gas compounds are those of xenon. Reason: The ionization enthalpy of xenon is very close to that of oxygen.
question_answer5) Assertion: Among the hydrides of nitrogen family, \[Bi{{H}_{3}}\] has the highest boiling point. Reason: The boiling point increases down the group because of increase in size.
question_answer6) Assertion: Noble gases are least reactive. Reason: Noble gases have completely filled s- and p-orbital and attain stable electronic configuration.
question_answer7) Assertion: Caro's acid has S atom in +6 oxidation state. Reason: Caro's acid contains one peroxo \[O_{2}^{2-}\] group.
question_answer8) Assertion: Halogens are coloured. Reason: Halogen molecules absorb some wavelength of visible light and the electrons are promoted to higher energy molecular orbitals.
question_answer9) Assertion: \[NO_{3}^{-}\] is planar while \[N{{H}_{3}}\] is pyramidal. Reason: N in \[NO_{3}^{-}\]is \[s{{p}^{2}}\]hybridized but in \[N{{H}_{3}}\] it is \[s{{p}^{3}}\] hybridized.
question_answer10) Assertion: Among nitrogen halides \[N{{X}_{3}}\] the dipole moment is highest for \[N{{I}_{3}}\] and lowest for \[N{{F}_{3}}\]. Reason: Nitrogen halides \[N{{X}_{3}}\], have trigonal pyramidal structure.
question_answer11) Assertion: \[C{{l}_{2}}\] gas bleaches the articles permanently. Reason: \[C{{l}_{2}}\] is a strong reducing agent.
question_answer12) Assertion: Xenon forms fluorides. Reason: Because 5d-orbitals are available for valence expansion.
question_answer13) Assertion: Sulphuric acid is more viscous than water. Reason: Concentrated sulphuric acid has a great affinity for water.
question_answer14) Assertion: Nitrogen is unreactive at room temperature but becomes reactive at elevated temperatures or in presence of a catalyst. Reason: In nitrogen molecule, there is extensive delocalization of electrons.
question_answer15) Assertion: All of the noble gases compounds are known except helium and neon. Reason: Ionisation potential values of helium and neon are close to xenon.
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