JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    KI and \[CuS{{O}_{4}}\] solution when mixed, give  [CPMT 2004; UPSEAT 2004]

    A) \[Cu{{I}_{2}}+{{K}_{2}}S{{O}_{4}}\]

    B) \[C{{u}_{2}}{{I}_{2}}+{{K}_{2}}S{{O}_{4}}\]

    C) \[{{K}_{2}}S{{O}_{4}}+C{{u}_{2}}{{I}_{2}}+{{I}_{2}}\]

    D) \[{{K}_{2}}S{{O}_{4}}+Cu{{I}_{2}}+{{I}_{2}}\]

    Correct Answer: C

    Solution :

    \[2KI+CuS{{O}_{4}}\to \underset{\text{Unstable}}{\mathop{Cu{{I}_{2}}}}\,+{{K}_{2}}S{{O}_{4}}\] \[2Cu{{I}_{2}}\to C{{u}_{2}}{{I}_{2}}+{{I}_{2}}\] Hence, solution contains \[C{{u}_{2}}{{I}_{2}},{{I}_{2}}\] and \[{{K}_{2}}S{{O}_{4}}\].


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