JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Electrode potential Ecell Nernst equation and ECS

  • question_answer
    The standard e.m.f. of a call, involving one electron change is found to be \[0.591\ V\] at 25°C. The equilibrium constant of the reaction is (\[F=96,500\ C\ mo{{l}^{-1}};\] \[R=8.314\ J{{K}^{-1}}mo{{l}^{-1}})\] [AIEEE 2004]

    A)                 \[1.0\times {{10}^{10}}\]             

    B)                 \[1.0\times {{10}^{5}}\]

    C)                 \[1.0\times {{10}^{1}}\]

    D)                 \[1.0\times {{10}^{30}}\]

    Correct Answer: A

    Solution :

               \[{{E}_{Cell}}=E_{Cell}^{0}-\frac{0.0591}{n}\log {{K}_{c}}\]                    At 298 K \[{{E}_{Cell}}=0\] \[O=0.591-\frac{0.0591}{n}\log {{K}_{c}}\]                                 \[\log {{K}_{c}}=\frac{0.591\times 1}{0.0591}=10\]; \[{{K}_{c}}=\text{Anti }\log 10=1\times {{10}^{10}}\].


You need to login to perform this action.
You will be redirected in 3 sec spinner