JEE Main & Advanced Chemistry Polymers / बहुलक Question Bank General methods of preparation and mechanism of Polymerisation

  • question_answer
    The degree of crystallinity of which of the following is highest

    A)                 Atactic polyvinylchloride              

    B)                 Isotactic polyvinylchloride

    C)                 Syndiotactic polyvinylchloride   

    D)                 All of these

    Correct Answer: C

    Solution :

           Syndiotactic polyvinylchloride \[\left( -C{{H}_{2}}-\underset{Cl\,\,\,}{\mathop{\underset{|\,\,\,\,\,\,\,}{\mathop{CH}}\,}}\,-C{{H}_{2}}-\overset{Cl\,\,}{\mathop{\overset{|\,\,\,\,\,\,}{\mathop{CH}}\,}}\,-C{{H}_{2}}-\underset{Cl\,}{\mathop{\underset{|\,\,\,\,}{\mathop{CH}}\,}}\,-C{{H}_{2}}-\overset{Cl\,\,\,}{\mathop{\overset{|\,\,\,\,\,}{\mathop{CH}}\,}}\, \right.\]\[-{{\left. C{{H}_{2}}-\underset{Cl\,\,\,\,\,\,\,}{\mathop{\underset{|\,\,\,\,\,\,}{\mathop{CH}}\,-}}\, \right)}_{n}}\] In this arrangement the chlorine atoms are alternately arranged. The polymer is stereoregular and has high crystallinity.


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