JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    If the heat of combustion of carbon monoxide at constant volume and at \[{{17}^{o}}C\] is ? 283.3 kJ, then its heat of combustion  at constant pressure \[(R=8.314\,J\,\text{degre}{{\text{e}}^{\text{-1}}}mo{{l}^{-1}})\]        [CPMT 2001]

    A)                 ? 284.5 kJ            

    B)                 284.5 kJ

    C)                 384.5 kJ

    D)                 ? 384.5 kJ

    Correct Answer: A

    Solution :

           \[C{{O}_{(g)}}+\frac{1}{2}{{O}_{2}}_{(g)}\to C{{O}_{(g)}},\Delta n=1-1+\frac{1}{2}=-\frac{1}{2}\]            \[\Delta H=\Delta E+\Delta nRT\]                                 \[\Delta H=-283.3-\frac{1}{2}\times \frac{8.314}{1000}\times 290=-284.5kJ\].


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