JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    For which one of the following equations is \[\Delta H_{\text{react}}^{o}\] equal to \[\Delta H_{f}^{o}\] for the product                [CBSE PMT  2003]

    A)                 \[2CO(g)+{{O}_{2}}(g)\,\to \,2C{{O}_{2}}(g)\]

    B)                 \[{{N}_{2}}(g)+{{O}_{3}}(g)\,\to \,{{N}_{2}}{{O}_{3}}(g)\]

    C)                 \[C{{H}_{4}}(g)+2C{{l}_{2}}(g)\,\to \,C{{H}_{2}}C{{l}_{2}}(l)+2HCl(g)\]

    D)                 \[Xe(g)+2{{F}_{2}}(g)\,\to \,Xe{{F}_{4}}(g)\]

    Correct Answer: D

    Solution :

              Both \[{{X}_{e}}\]and \[{{F}_{2}}\]are gaseous elements at \[{{25}^{o}}C\] and in their standard states and form \[Xe{{F}_{4(g)}}\] hence \[\Delta H_{(f)}^{\circ }=\Delta H_{\text{react}}^{\circ }\].


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