JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    If \[\Delta H_{f}^{o}\] for \[{{H}_{2}}{{O}_{2}}\] and \[{{H}_{2}}O\] are \[-188\,kJ/mole\] and \[-286\,kJ/mole\]. What will be the enthalpy change of the reaction \[2{{H}_{2}}{{O}_{2}}(l)\to 2{{H}_{2}}O(l)+{{O}_{2}}(g)\]        [MP PMT 1992]

    A)                 \[-196\,kJ/mole\]           

    B)                 \[146\,kJ/mole\]

    C)                 \[-494\,kJ/mole\]           

    D)                 \[-98\,kJ/mole\]

    Correct Answer: A

    Solution :

           \[{{H}_{2}}+{{O}_{2}}\to {{H}_{2}}{{O}_{2}}\]   \[\Delta H_{f}^{o}=-188\,kJ/mole\]    ?.(i)            \[{{H}_{2}}+\frac{1}{2}{{O}_{2}}\to {{H}_{2}}O\] \[\Delta H_{f}^{o}=-286\,kJ/mole\]            ?.(ii)                                 eq. (i) ? eq. (ii) × 2 gives the required result.


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