JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    The enthalpy of combustion at 25°C of H2, cyclohexane (C6H12) and cyclohexene (C6H10) are ?241, ?3920 and ?800 KJ / mole respectively. The heat of hydrogenation of cyclohexene is                [BHU 2005]

    A)                 ? 121 KJ / mole 

    B)                 + 121 KJ / mole

    C)                 ? 242 KJ / mole 

    D)                 + 242 KJ / mole

    Correct Answer: A

    Solution :

                      (i)   \[{{H}_{2}}+\frac{1}{2}{{O}_{2}}\to {{H}_{2}}O,\,\,\Delta H=-241\,kJ\]            (ii)  \[{{C}_{6}}{{H}_{10}}+\frac{17}{2}{{O}_{2}}\to 6C{{O}_{2}}+5{{H}_{2}}O,\,\Delta H=-3800\,kJ\]            (iii) \[{{C}_{6}}{{H}_{12}}+9{{O}_{2}}\to 6C{{O}_{2}}+6{{H}_{2}}O,\,\,\Delta H=-3920\,kJ\]                    \[{{C}_{6}}{{H}_{10}}+{{H}_{2}}\to {{C}_{6}}{{H}_{12}}\]                    Eq. (i) + Eq. (ii) ? Eq. (iii)                    \[\Delta H=-241-3800-(-3920)\]                                 \[=-4041+3920=-121\,kJ\]


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