JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    A solution of \[500ml\] of \[0.2\,M\,KOH\] and \[500\,ml\] of \[0.2\,M\,HCl\] is mixed and stirred; the rise in temperature is \[{{T}_{1}}\]. The experiment is repeated using \[250\,ml\] each of solution, the temperature raised is \[{{T}_{2}}\]. Which of the following is true      [EAMCET 1987; MP PET 1994]

    A)                 \[{{T}_{1}}={{T}_{2}}\]  

    B)                 \[{{T}_{1}}=2{{T}_{2}}\]

    C)                 \[{{T}_{1}}=4{{T}_{2}}\]

    D)                 \[{{T}_{2}}=9{{T}_{1}}\]

    Correct Answer: A

    Solution :

           Suppose heat evolved in Ist case is \[{{Q}_{1}}\] and that in the IInd case it is \[{{Q}_{2}}\]. Then \[{{Q}_{2}}=\frac{1}{2}{{Q}_{1.}}\]            But \[{{Q}_{1}}=1000\,{{T}_{1}}\] and \[{{Q}_{2}}=500\,{{T}_{2}}\]                                 \[\therefore 500\,\,{{T}_{2}}=\frac{1}{2}\times 1000\,\,{{T}_{1}}\,\,i.e.\,{{T}_{2}}={{T}_{1}}\].


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