JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Heat of reaction

  • question_answer
    Carbon and carbon monoxide burn in oxygen to form carbon dioxide according to the following reactions                 \[C+{{O}_{2}}\to C{{O}_{2}};\,\Delta H=-394\,kJ\,mo{{l}^{-1}}\]                 \[2CO+{{O}_{2}}\to 2C{{O}_{2}};\,\Delta H=-569\,kJ\,mo{{l}^{-1}}\]                 The heat of formation of \[1\,mol\]of carbon monoxide is thus [MP PET 1995]

    A)                 \[-219.0\,kJ\,mo{{l}^{-1}}\]        

    B)                 \[-109.5\,kJ\,mo{{l}^{-1}}\]

    C)                 \[-175.0\,kJ\,mo{{l}^{-1}}\]        

    D)                 \[-87.5\,kJ\,mo{{l}^{-1}}\]

    Correct Answer: B

    Solution :

           \[C+{{O}_{2}}\to C{{O}_{2}}+394\,kJ\].                    \[2C+2{{O}_{2}}\to 2C{{O}_{2}}+788\,kJ\]                          ?.(i)                    \[2CO+{{O}_{2}}\to 2C{{O}_{2}}+569\,kJ\]                         ?.(ii)                    \[2C{{O}_{2}}\to 2CO+{{O}_{2}}-569\,kJ\]                          ?..(iii)                                 eq. (i) + eq. (iii) = ?109.5 kJ mol?1.


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