JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Kp and Kc Relationship and Characteristics of K

  • question_answer
    The equilibrium constant for the reversible reaction, \[{{N}_{2}}+3{{H}_{2}}\] ⇌ \[2N{{H}_{3}}\] is \[K\] and for the reaction \[\frac{1}{2}{{N}_{2}}+\frac{3}{2}{{H}_{2}}\] ⇌ \[N{{H}_{3}}\] the equilibrium constant is \[{K}'\]. \[K\] and \[{K}'\] will be related as                            [MP PET 1997]

    A)                 \[K={K}'\]           

    B)                 \[{K}'=\sqrt{K}\]

    C)                 \[K=\sqrt{{{K}'}}\]           

    D)                 \[K\times {K}'=1\]

    Correct Answer: B

    Solution :

           \[{K}'={{K}^{n}};\] Hence \[n=\frac{1}{2}\]                 \[\therefore \,\,{K}'={{K}^{1/2}}=\sqrt{K}\]


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