12th Class Chemistry Solutions / विलयन Question Bank MCQs - Solutions

  • question_answer
    \[{{H}_{2}}S\]is a toxic gas used in qualitative analysis. If solubility of \[{{H}_{2}}S\] in water at STP is 0.195 m, what is the value of \[{{K}_{H}}\]?

    A) 0.0263 bar

    B) 69.16 bar

    C) 192 bar

    D) 282 bar

    Correct Answer: D

    Solution :

    No. of moles of \[{{H}_{2}}S=0.195\] No. of moles of \[{{H}_{2}}O=\frac{1000}{18}=55.55\] Mole fraction of  \[{{H}_{2}}S=~\frac{0.195}{0.195+55.55}=\text{ }0.0035\] Pressure at STP = 0.987 bar According to Henry's law, p = \[{{K}_{H}}x\] Or \[{{K}_{H}}=\frac{P{{H}_{2}}S}{X{{H}_{2}}S}=\frac{0.987}{0.0035}=282\,bar\]


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