JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Mock Test - Chemical Equilibrium

  • question_answer
    The dissociation equilibrium of a gas \[A{{B}_{2}}\]can be represented as \[2A{{B}_{2}}(g)\rightleftarrows 2AB(g)+{{B}_{2}}(g)\]The degree of dissociation is x and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant \[{{K}_{P}}\]and total pressure p is

    A) \[{{(2{{K}_{P}}/P)}^{1/3}}\]  

    B) \[{{(2{{K}_{P}}/P)}^{1/2}}\]

    C) \[({{K}_{P}}/P)\]                      

    D) \[(2{{K}_{P}}/P)\]

    Correct Answer: A

    Solution :

    [a] \[\underset{\underset{1-x}{\mathop{1}}\,}{\mathop{2A{{B}_{2}}}}\,(g)\rightleftharpoons \underset{\underset{x}{\mathop{0}}\,}{\mathop{2AB}}\,(g)+\underset{\underset{x/2}{\mathop{0}}\,}{\mathop{{{B}_{2}}}}\,(g)\] \[\therefore Kp=\frac{{{x}^{2}}.x}{2{{(1-x)}^{2}}}.\left[ \frac{P}{1+\frac{x}{2}} \right]=\frac{{{x}^{2}}.P}{2}\] \[(1-x\approx 1\,and\,1+\frac{x}{2}\approx 1,Since\,x<<1)\] Or \[P=\sqrt[3]{\frac{2Kp}{P}}\]


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