JEE Main & Advanced Chemistry Chemical Kinetics / रासायनिक बलगतिकी Question Bank Mock Test - Chemical Kinetics

  • question_answer
          The specific rate constant of the decomposition of \[{{N}_{2}}{{O}_{5}}\] is 0.008\[{{\min }^{-1}}\]. The volume of \[{{O}_{2}}\]collected after 20 minutes is 16 mL. find the volume that would be collected at the end of reaction. \[N{{O}_{2}}\]formed is dissolved in \[CC{{l}_{4}}\]

    A) 17.49 mL         

    B) 27.49 mL

    C) 37.49 mL         

    D) 47.49 mL

    Correct Answer: A

    Solution :

    [a] Given k = 0.008 \[{{\min }^{-1}}\] From \[\therefore k=\frac{2.303}{t}\log \frac{{{V}_{\infty }}}{{{V}_{\infty }}-{{V}_{t}}}\] \[\Rightarrow 0.008=\frac{2.303}{20}\log \frac{{{V}_{\infty }}}{{{V}_{\infty }}-16}\] \[\Rightarrow 0.0695=\log \frac{{{V}_{\infty }}}{{{V}_{\infty }}-16}\] \[\Rightarrow {{V}_{\infty }}=17.49mL\]


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