JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Mock Test - Electrochemistry

  • question_answer
    The standard emf of a cell having one electron change found to be 0.591 V at \[25{}^\circ C\]. The equilibrium constant the reaction is

    A) \[1.0\times {{10}^{30}}\]         

    B) \[1.0\times {{10}^{5}}\]

    C) \[1.0\times {{10}^{10}}\]         

    D) \[1.0\times {{10}^{1}}\]

    Correct Answer: C

    Solution :

    [c] \[{{E}_{cell}}={{E}^{o}}_{cell}-\frac{0.059}{n}\log Q\] At equilibrium, \[{{E}_{cell}}=0\]and \[Q={{K}_{c}}\] \[{{E}^{o}}_{cell}=\frac{0.059}{1}\log {{K}_{c}}\] \[\Rightarrow 0.591=\frac{0.059}{1}\log {{K}_{c}}\] \[\therefore {{K}_{c}}=1\times {{10}^{10}}\]


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