JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Mock Test - Electrochemistry

  • question_answer
    The standard potential at 298 K for the following half reactions are given against each:
    \[Z{{n}^{2+}}(aq)+2{{e}^{-}}\rightleftharpoons Zn(s)\] \[-\,0.762\text{ }V\]
    \[2{{H}^{+}}(aq)+2{{e}^{-}}\rightleftharpoons {{H}_{2}}(g)\]            0.000 V
    \[C{{r}^{3+}}(aq)+3{{e}^{-}}\rightleftharpoons Cr(s)\] \[-\,0.740\text{ }V\]
    \[F{{e}^{3+}}(aq)+2{{e}^{-}}\rightleftharpoons F{{e}^{2+}}(aq)\]    0.770 V
    Which is the strongest reducing agent?

    A) Zn(s)                

    B) Cr(s)

    C) \[{{H}_{2}}\left( g \right)\]         

    D) \[F{{e}^{2+}}\left( aq \right)\]

    Correct Answer: A

    Solution :

    [a] The more negative the standard potential, the least the reduction tendency of the ion. The corresponding atom has largest oxidation tendency and thus is a strong reducing agent. In the present case. Zn is the strongest reducing agent.


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