JEE Main & Advanced Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन Question Bank Mock Test - Organic Chemistry : Some Basic Principles and Techniques

  • question_answer
    The stability order of following carbocation is

    A) i> ii> iv> iii    

    B) iii> i> ii> iv

    C) iv> ii> iii> i    

    D) ii> iv> iii> i

    Correct Answer: D

    Solution :

    [d] (i) Bridgehead carbocations are unstable due to Bredt?s rule. Stability of carbocation \[\propto +I\]effect s-character \[\propto \]electronegativity \[\propto +\frac{I}{+Ieffect}\] Thus (iii) is least stable Stability order of carbocation is \[3{}^\circ >2{}^\circ >1{}^\circ \] Order of stability (ii)> (iv)> (iii)> (i)


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