JEE Main & Advanced Chemistry States of Matter / पदार्थ की अवस्थाएँ - गैस एवं द्रव Question Bank Mock Test - States of Matter

  • question_answer
    Two gases A and B present separately in two vessels X and Y at the same temperature with molecular weights M and 2M respectively are effused out. The orifice in vessel X is circular while that in Vis a square. If the radius of the circular orifice is equal to that of the length of the square orifice, the ratio of rates of effusion of gas A to that of gas B is

    A) \[\sqrt{2}\pi \]  

    B) \[\sqrt{\frac{\pi }{2}}\]

    C) \[2\pi \]            

    D) \[\sqrt{\frac{2}{\pi }}\]

    Correct Answer: A

    Solution :

    [a] \[\frac{{{r}_{x}}}{{{r}_{y}}}=\sqrt{\frac{2M}{M}}\times \frac{{{A}_{x}}}{{{A}_{y}}}\]where \[{{A}_{x}}\]and \[{{A}_{y}}\]are the area of section of orifice. \[\therefore \frac{{{r}_{x}}}{{{r}_{y}}}=\sqrt{2}\times \frac{\pi {{r}^{2}}}{{{\ell }^{2}}}r=\]radius of a radius orifice \[\ell \]= length of square orifice \[\frac{{{r}_{x}}}{{{r}_{y}}}=\sqrt{2}\times \pi \]


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