JEE Main & Advanced Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना Question Bank Molecular orbital theory

  • question_answer
    Which of the following molecule is paramagnetic                         [CPMT 1980; RPET 1999;MP PMT 1999; RPMT 2000]

    A)                 Chlorine              

    B)                 Nitrogen

    C)                 Oxygen               

    D)                 Hydrogen

    Correct Answer: C

    Solution :

               Oxygen is paramagnetic due to the presence of two unpaired electron:                 \[{{O}_{2}}=\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\] \[\sigma {{(2{{p}_{x}})}^{2}}\pi {{(2{{p}_{y}})}^{2}}\pi {{(2{{p}_{x}})}^{2}}{{\pi }^{*}}{{(2{{p}_{y}})}^{1}}{{\pi }^{*}}{{(2{{p}_{z}})}^{1}}\]


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