A) \[C{{H}_{3}}COCl\]
B) \[CHC{{l}_{2}}COOH\]
C) \[C{{H}_{2}}ClCOOH\]
D) \[C{{H}_{3}}COOCl\]
Correct Answer: A
Solution :
When acetic acid is reacted with \[PC{{l}_{5}}\] the product formed are acetyl chloride, phosphoryl chloride and hydrochloric acid \[\underset{Acetic\,acid}{\mathop{C{{H}_{3}}COOH}}\,+\underset{\begin{smallmatrix} Phosphorus \\ Penta\,chloride \end{smallmatrix}}{\mathop{PC{{l}_{5}}}}\,\to \underset{\begin{smallmatrix} Acetyl \\ Chloride \end{smallmatrix}}{\mathop{C{{H}_{3}}COCl}}\,+\underset{\begin{smallmatrix} Hydro- \\ Chloric \\ acid \end{smallmatrix}}{\mathop{HCl}}\,+\underset{\begin{smallmatrix} Phosphoryl \\ chloride \end{smallmatrix}}{\mathop{POC{{l}_{3}}}}\,\]
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