JEE Main & Advanced Chemistry Aldehydes, Ketones Question Bank Properties

  • question_answer
    Cyanohydrin of which of the following forms lactic acid [MHCET 2003]

    A)                 \[C{{H}_{3}}C{{H}_{2}}CHO\]     

    B)                 \[C{{H}_{3}}CHO\]

    C)                 \[HCHO\]            

    D)                 \[C{{H}_{3}}COC{{H}_{3}}\]

    Correct Answer: B

    Solution :

               We know that            \[\underset{\text{Acetaldehyde}}{\mathop{\overset{\overset{\,\,\,\,\,H}{\mathop{\,\,\,\,\,\,\,|}}\,}{\mathop{C{{H}_{3}}-C=O}}\,}}\,\xrightarrow{+HCN}\underset{\text{Cyanohydrin}}{\mathop{\underset{\underset{\,\,\,CN}{\mathop{\,\,\,|}}\,}{\mathop{\overset{\overset{\,\,\,\,H}{\mathop{\,\,\,\,|}}\,}{\mathop{C{{H}_{3}}-C-OH}}\,}}\,}}\,\xrightarrow{+{{H}_{2}}O}\]\[\underset{\text{Lactic acid}}{\mathop{\underset{\underset{\,\,COOH}{\mathop{\,\,\,|}}\,}{\mathop{\overset{\overset{\,\,\,H}{\mathop{\,\,\,|}}\,}{\mathop{C{{H}_{3}}-C-OH}}\,}}\,}}\,\]                 Thus Lactic acid is formed.


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