JEE Main & Advanced Chemistry Aldehydes, Ketones Question Bank Properties

  • question_answer
    Benzyl alcohol and sodium benzoate is obtained by the action of sodium hydroxide on benzaldehyde. This reaction is known as                                             [KCET 2005]

    A) Perkin's reaction             

    B) Cannizzaro's reaction

    C) Sandmeyer's reaction   

    D) Claisen condensation

    Correct Answer: B

    Solution :

    Benzaldehyde on treatment with 50% aqueous or ethanolic alkali solution undergoes Cannizzaro?s reaction like \[HCHO\] (no \[\alpha \]-hydrogen atom) i.e., one molecule is oxidised and one is reduced with the formation of benzoic acid and benzyl alcohol respectively.                                \[2{{C}_{6}}{{H}_{5}}CHO\xrightarrow{NaOH}{{C}_{6}}{{H}_{5}}C{{H}_{2}}OH+{{C}_{6}}{{H}_{5}}COONa\]


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