JEE Main & Advanced Chemistry Aldehydes, Ketones Question Bank Properties

  • question_answer
    A and B in the following reactions are \[R-\underset{\underset{O}{\mathop{||}}\,}{\mathop{C}}\,-{R}'\underset{KCN}{\mathop{\xrightarrow{HCN}}}\,A\xrightarrow{B}\begin{matrix}    R  \\    R  \\ \end{matrix}\,>C<\begin{array}{*{35}{l}}    OH  \\    C{{H}_{2}}N{{H}_{2}}  \\ \end{array}\] [CBSE PMT 2003]

    A)                 \[A=RR'C<\begin{matrix}    CN  \\    OH  \\ \end{matrix},B-LiAl{{H}_{4}}\]

    B)                 \[A=RR'C<\begin{array}{*{35}{l}}    OH  \\    COOH  \\ \end{array},\,\,B-N{{H}_{3}}\]

    C)                 \[A=RR'C<\begin{matrix}    CN  \\    OH  \\ \end{matrix}\ ,B={{H}_{3}}{{O}^{\oplus }}\]

    D)                 \[A=RR'C{{H}_{2}}CN,B=NaOH\]

    Correct Answer: A

    Solution :

               \[R-CO-R\,'\xrightarrow{HCN}R-\underset{\text{(}A\text{)}}{\mathop{\underset{_{CN}^{\,|}\,\,\,\,\,}{\overset{_{\,|}^{OH}\,\,\,\,}{\mathop{C-R\,'}}}\,}}\,\xrightarrow{LiAl{{H}_{4}}}\]                 \[R-\underset{_{R\,'}^{\,|}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}{\overset{_{\,|}^{OH}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}{\mathop{C-C{{H}_{2}}N{{H}_{2}}}}}\,\]


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