NEET Chemistry Aldehydes, Ketones Question Bank Self Evaluation Test - Aldehydes, Ketons and Carboxylic Acids

  • question_answer
    Which of the following will not give butyl acetate when treated with 1-butanol

    A) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-Cl\left( pyridene \right)\]

    B) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-OH\left( {{H}_{2}}S{{O}_{4}} \right)\]

    C) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-C{{H}_{3}}\left( pyridene \right)\]

    D) \[C{{H}_{3}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-H\left( {{H}_{2}}S{{O}_{4}} \right)\]

    Correct Answer: D

    Solution :

    [d] Acid chlorides, anhydrides, acids give ester with alcohol \[ROH+R'COCI\xrightarrow{{}}ROCOR'+HCl\] \[ROH+{{\left( R'CO \right)}_{2}}O\xrightarrow{{}}ROCOR'+RCOOH\] \[ROH+{R}'COOH\xrightarrow{{}}ROCO{R}'+{{H}_{2}}O\]


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