NEET Chemistry Chemical Kinetics / रासायनिक बलगतिकी Question Bank Self Evaluation Test - Chemical Kinetics

  • question_answer
    In a reaction at \[27{}^\circ C,{{10}^{-3}}\]% reactant molecules manage to cross over the barrier of transition state. The energy of these molecules in excess of the average value will be \[(R=2cal\text{ }{{K}^{-1}}\text{ }mo{{l}^{-1}})\]:

    A) \[6.91\text{ kc}al\text{ }mo{{l}^{-1}}\]   

    B) \[3.00\text{ kc}al\text{ }mo{{l}^{-1}}\]

    C) \[4.15\,kcal\,mo{{l}^{-1}}\]      

    D) \[5.10kcal\,mo{{l}^{-1}}\]

    Correct Answer: A

    Solution :

    [a] \[{{e}^{-{{E}_{a}}/RT}}={{10}^{-3}}\]% \[={{10}^{-5}};\] \[{{E}_{a}}=2.303\times 2\times 300\times 5\,cal\] \[=6.91 kcal/mo{{\operatorname{l}}^{-1}}\]


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