NEET Chemistry Chemical Kinetics / रासायनिक बलगतिकी Question Bank Self Evaluation Test - Chemical Kinetics

  • question_answer
    In a chemical reaction A is converted into B. The rates of reaction, starting with initial concentrations of A as \[2\times {{10}^{-3}}M\] and \[1\times {{10}^{-3}}M,\] are equal to \[2.40\times {{10}^{-4}}M{{s}^{-1}}\] and \[0.60\times {{10}^{-4}}M{{s}^{-1}}\] respectively. The order of reaction with respect to reactant A will be

    A) 0                                 

    B) 1.5   

    C) 1                                 

    D) 2

    Correct Answer: D

    Solution :

    [d]        \[a\xrightarrow{{}}B\]    \[\begin{align}   & \begin{matrix}    \text{Initial concentration} & \text{Rate of reaction}  \\ \end{matrix} \\  & \begin{matrix}    2\times {{10}^{-3}}M & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,2.40\times {{10}^{-4}}M{{s}^{-1}}  \\ \end{matrix} \\  & \begin{matrix}    1\times {{10}^{-3}}M & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,0.60\times {{10}^{-4}}M{{s}^{-1}}  \\ \end{matrix} \\ \end{align}\]  rate of reaction \[r=k{{[A]}^{x}}\] where x = order of reaction hence \[2.40\times {{10}^{-4}}=k{{\left[ 2\times {{10}^{-3}} \right]}^{x}}\]              ......(i) \[0.60\times {{10}^{-4}}=k{{[1\times {{10}^{-3}}]}^{x}}\]   ......(ii)             On dividing eqn.(i) from eqn. (ii) we get \[4={{(2)}^{x}}\] \[\therefore ~~x=2\] i.e. order of reaction = 2


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