NEET Chemistry Coordination Chemistry Question Bank Self Evaluation Test - Co-ordination Compounds

  • question_answer
    In the silver plating of copper, \[K[Ag{{\left( CN \right)}_{2}}]\] is used instead of\[AgN{{O}_{3}}\]. The reason is

    A) a thin layer of Ag is formed on Cu

    B) more voltage is required

    C) \[A{{g}^{+}}\] ions are completely removed from solution

    D) less availability of \[A{{g}^{+}}\] ions, as Cu cannot displace Ag from \[{{[Ag{{(CN)}_{2}}]}^{-}}\] ion.

    Correct Answer: D

    Solution :

    [d] In silver plating \[K[Ag{{(CN)}_{2}}]\] is used which provides constant and required supply of \[A{{g}^{+}}\] ions as \[Ag{{(CN)}_{2}}^{-}\] is very stable. But if \[AgN{{O}_{3}}\] is used concentration of \[[A{{g}^{+}}]\] in solution will be very large. In that case Ag will be deposited at faster rate without any uniformity.


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