JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    8 mol of \[A{{B}_{3}}(g)\]are introduced into a \[1.0\text{ }d{{m}^{3}}\]vessel. If it dissociates as \[2A{{B}_{3}}(g)\rightleftharpoons {{A}_{2}}(g)+3{{B}_{2}}(g)\]. At equilibrium, 2 mol of \[{{A}_{2}}\] are found to be present. The equilibrium. constant of this reaction is

    A) 2                     

    B) 3     

    C) 27                    

    D) 36

    Correct Answer: C

    Solution :

    [c]  \[\begin{align}   & \begin{matrix}    {} & {} & {} & 2A{{B}_{3}}(g)\rightleftharpoons {{A}_{2}}(g)+3{{B}_{2}}(g)  \\ \end{matrix} \\  & \begin{matrix}    at\,t=0 & {} & 8 & \begin{matrix}    {} & {} & 0 & \begin{matrix}    {} & \begin{matrix}    {} & 0  \\ \end{matrix}  \\ \end{matrix}  \\ \end{matrix}  \\ \end{matrix} \\  & \begin{matrix}    at\,eq. & (8-2\times 2) & {} & \begin{matrix}    2 & \begin{matrix}    {} & 3\times 2  \\ \end{matrix}  \\ \end{matrix}  \\ \end{matrix} \\  & \begin{matrix}    {} & {} & {} & \begin{matrix}    =4 & {} & {} & \begin{matrix}    \begin{matrix}    2 & {} & {}  \\ \end{matrix} & 6  \\ \end{matrix}  \\ \end{matrix}  \\ \end{matrix} \\ \end{align}\] now \[{{K}_{C}}=\frac{\left[ {{A}_{2}} \right]{{\left[ {{B}_{2}} \right]}^{3}}}{{{\left[ A{{B}_{3}} \right]}^{2}}}=\frac{2/1\times {{[6/1]}^{3}}}{{{[4/1]}^{2}}}=27\]


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