JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    For the equilibrium system \[2HX(g)\rightleftharpoons {{H}_{2}}(g)+{{X}_{2}}(g)\] the equilibrium constant is \[1.0\times {{10}^{-5}}\]. What is the concentration of HX if the equilibrium concentration of \[{{H}_{2}}\] and \[{{X}_{2}}\] are\[1.2\times {{10}^{-3}}M\], and \[1.2\times {{10}^{-4}}M\] respectively.

    A) \[12\times {{10}^{-4}}M\]        

    B) \[12\times {{10}^{-3}}M\]

    C) \[12\times {{10}^{-2}}M\]        

    D) \[12\times {{10}^{-1}}M\]

    Correct Answer: C

    Solution :

    [c] At eqm. \[\begin{align}   & 2HX(g)\rightleftharpoons \,\,\,\,\,\,\,\,\,\,\,\,\,\,{{H}_{2}}(g)\,\,\,\,\,+\,\,\,\,\,{{X}_{2}}(g) \\  & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,1.2\times {{10}^{-3}}M\,\,\,\,\,\,\,\,1.2\times {{10}^{-4}}M \\ \end{align}\] \[{{K}_{eq}}=\frac{[{{H}_{2}}][{{X}_{2}}]}{{{[HX]}^{2}}}\] \[{{10}^{-5}}=\frac{1.2\times {{10}^{-3}}\times 1.2\times {{10}^{-4}}}{{{[HX]}^{2}}}\] \[[HX]=\sqrt{\frac{1.2\times 1.2\times {{10}^{-7}}}{{{10}^{-5}}}}\] \[=1.2\times {{10}^{-1}}\] \[=12\times {{10}^{-2}}M\]


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