JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    If 1.0 mole of \[{{I}_{2}}\] is introduced into 1.0 litre flask at 1000 K, at quilibrium \[({{K}_{c}}={{10}^{-6}})\], which one is correct

    A) \[\left[ {{I}_{2}}(g) \right]>\left[ {{I}^{-}}\left( g \right) \right]\]  

    B) \[\left[ {{I}_{2}}(g) \right]<\left[ {{I}^{-}}\left( g \right) \right]\]

    C) \[\left[ {{I}_{2}}(g) \right]=\left[ {{I}^{-}}\left( g \right) \right]\]  

    D) \[\left[ {{I}_{2}}(g) \right]=\frac{1}{2}\left[ {{I}^{-}}\left( g \right) \right]\]

    Correct Answer: A

    Solution :

    [a]  \[\begin{align}   & {{I}_{2}}\rightleftharpoons 2{{I}^{-}} \\  & \begin{matrix}    1-x & 2x  \\ \end{matrix} \\ \end{align}\] \[{{K}_{c}}=\frac{{{(2x)}^{2}}}{(1-x)}={{10}^{-6}}\] Soln. shows that \[(1-x)>2x\] \[\therefore [{{I}_{2}}(g)]>[I{{  }^{-}}(g)]\]


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