JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    In a saturated solution of the sparingly soluble strong electrolyte \[AgI{{O}_{3}}\](molecular mass = 283) the equilibrium which sets is \[AgI{{O}_{3}}(s)\rightleftharpoons A{{g}^{+}}(aq)+IO_{3}^{-}(aq).\] If the solubility product constant \[{{K}_{sp}}\] of \[AgI{{O}_{3}}\] at a given temperature is \[1.0\times {{10}^{-8}}\], what is the mass of \[AgI{{O}_{3}}\] contained in 100 mL of its saturated solution?

    A) \[1.0\times {{10}^{-4}}\]g    

    B) \[28.3\times {{10}^{-2}}g\]

    C) \[2.83\times {{10}^{-3}}g\]      

    D) \[1.0\times {{10}^{-7}}g.\]

    Correct Answer: C

    Solution :

    [c] Let s = solubility \[AgI{{O}_{3}}\rightleftharpoons \underset{s}{\mathop{A{{g}^{+}}}}\,+\underset{s}{\mathop{IO_{3}^{-}}}\,\] \[{{K}_{sp}}=[A{{g}^{+}}][I{{O}_{3}}^{-}]=s\times s={{s}^{2}}\] Given \[{{K}_{sp}}=1\times {{10}^{-8}}\] \[\therefore s=\sqrt{{{K}_{sp}}}=\sqrt{1\times {{10}^{-8}}}\] \[=1.0\times {{10}^{-4}}mol/lit=1.0\times {{10}^{-4}}\times 283\text{ }g/lit\] (\[\therefore \]Molecular mass of\[AgI{{O}_{3}}=283\]) \[=\frac{1.0\times {{10}^{-4}}\times 283\times 100}{1000}g/100mL\] \[=2.83\times {{10}^{-3}}g/100mL\]


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