JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    A solution of \[N{{H}_{4}}Cl\] and \[N{{H}_{3}}\] has pH = 8.0. Which of the following hydroxides may be precipitated when this solution is mixed with equal volume of 0.2 M of metal ion.

    A) \[Ba{{\left( OH \right)}_{2}}\left( {{K}_{sp}}=1.1\times {{10}^{-4}} \right)\]

    B) \[Mg{{\left( OH \right)}_{2}}\left( {{K}_{sp}}=3.5\times {{10}^{-4}} \right)\]

    C) \[Fe{{(OH)}_{2}}\left( {{K}_{sp}}=8.1\times {{10}^{-16}} \right)\]

    D) \[Ca{{\left( OH \right)}_{2}}\left( {{K}_{sp}}=2.1\times {{10}^{-5}} \right).\]

    Correct Answer: C

    Solution :

    [c] \[pH=8,pOH=6;[O{{H}^{-}}]={{10}^{-6}}M\] Ionic product of \[Fe{{(OH)}_{2}}=0.2\times {{(1\times {{10}^{-6}})}^{2}}\] \[=2\times {{10}^{-13}}>{{K}_{sp}}\left( =8.1\times {{10}^{-16}} \right)\]


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