JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Self Evaluation Test - Equilibrium

  • question_answer
    Solid \[AgN{{O}_{3}}\] is slowly added to a solution containing each of 0.01M \[NaCl\] and 0.001 M \[NaBr.\] What will be the concentration of \[{{C}^{-}}\] ions in solution when \[AgBr\] will just start to precipitate? \[{{K}_{sp}}(AgBr)=3.6\times {{10}^{-13}},{{K}_{sp}}(AgCl)=1.8\times {{10}^{-10}}.\]

    A) \[1.8\times {{10}^{-7}}\]         

    B) \[3.6\times {{10}^{-10}}\]

    C) 0.01                             

    D) \[2\times {{10}^{-4}}\]

    Correct Answer: C

    Solution :

    [c] \[{{K}_{sp}}(AgBr)<{{K}_{sp}}(AgCl)\] Therefore, \[AgBr\] will precipitate first and at that time all \[C{{l}^{-}}\] will be present.


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