JEE Main & Advanced Chemistry Some Basic Concepts of Chemistry / रसायन की कुछ मूलभूत अवधारणाएँ Question Bank Self Evaluation Test - Some Basic Concepts of Chemistry

  • question_answer
    What is the molarity of \[SO_{4}^{2-}\] ion in aqueous solution that contain 34.2 ppm of \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}\]? (Assume complete dissociation and density of solution 1 g/mL)  

    A) \[3\times {{10}^{-4}}M\]      

    B) \[2\times {{10}^{-4}}M\]

    C) \[{{10}^{-4}}M\]                    

    D) None of these

    Correct Answer: A

    Solution :

    [a]
    \[\frac{mass\text{ }of\text{ }A{{l}_{2}}{{\left( S{{O}_{4}} \right)}_{3}}}{mass\text{ }of\text{ }water}\times {{10}^{6}}=34.2\]
    1 litre solution contains 1000 g of water
    \[\Rightarrow \] In 1 litre solution, mass of \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}=\frac{34.2\times 1000}{{{10}^{6}}}=34.2mg\]
    Molarity of \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}=\frac{34.2\times {{10}^{-3}}}{342}M={{10}^{-4}}M\]
    \[\underset{{{10}^{\,-\,4}}M}{\mathop{A{{l}_{2}}{{(S{{O}_{4}})}_{3}}}}\,(aq)\xrightarrow{{}}\underset{2\,\,\times \,\,{{10}^{-4}}M\,\,\,\,\,\,\,\,\,\,\,3\,\,\times \,\,{{10}^{-4}}M}{\mathop{2A{{l}^{3+}}(aq)+3SO_{4}^{2-}(aq)}}\,]\,\,\,\,\,\,[\left[ SO_{4}^{2-} \right]=3\times {{10}^{-4}}M]\text{ }\!\!~\!\!\text{ }\]


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