JEE Main & Advanced Chemistry Some Basic Concepts of Chemistry / रसायन की कुछ मूलभूत अवधारणाएँ Question Bank Self Evaluation Test - Some Basic Concepts of Chemistry

  • question_answer
    Number of moles of \[KMn{{O}_{4}}\] required to oxidize one mole of \[Fe({{C}_{2}}{{O}_{4}})\] in acidic medium is

    A) 0.167   

    B) 0.6    

    C) 0.2                   

    D) 0.4

    Correct Answer: B

    Solution :

    [b] The required equation is \[2KMn{{O}_{4}}+3{{H}_{2}}S{{O}_{4}}\xrightarrow{{}}\]\[{{K}_{2}}S{{O}_{4}}+2MnS{{O}_{4}}+3{{H}_{2}}O+~\underset{nascent\text{ }oxygen}{\mathop{5\left[ O \right]}}\,\]
    \[2Fe\left( {{C}_{2}}{{O}_{4}} \right)+3{{H}_{2}}S{{O}_{4}}+3\left[ O \right]\xrightarrow{{}}\]\[F{{e}_{2}}{{\left( S{{O}_{4}} \right)}_{3}}+2C{{O}_{2}}+3{{H}_{2}}O\]
    \[O\] required for 1 mol. of \[Fe({{C}_{2}}{{O}_{4}})\] is 1.5,5 \[O\] are obtained from 2 moles of \[KMn{{O}_{4}}\]
    \[\therefore 1.5\text{ }\left[ O \right]\] will be obtained from \[=\frac{2}{5}\times 1.5=0.6\] moles of \[KMn{{O}_{4}}\].


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