NEET Chemistry States of Matter / पदार्थ की अवस्थाएँ - गैस एवं द्रव Question Bank Self Evaluation Test - States of Matter

  • question_answer
    van der Waal's equation for a gas is stated as, \[P=\frac{nRT}{V-nb}-a{{\left( \frac{n}{V} \right)}^{2}}.\] This equation reduces to the perfect gas equation, \[P=\frac{nRT}{V}\]

    A) temperature is sufficient high and pressure is low.

    B) temperature is sufficient low and pressure is high.

    C) both temperature and pressure are very high.

    D) both temperature and pressure are very low.

    Correct Answer: A

    Solution :

    [a] Given \[P=\frac{nRT}{V-nb}-a{{\left( \frac{n}{V} \right)}^{2}}\] Which can also be written as \[\left[ P+\frac{{{n}^{2}}a}{{{V}^{2}}} \right](V-nb)=nRT\] At low pressure and high temperature the a effect of \[\frac{a}{{{V}^{2}}}\] and b is negligible hence \[PV=nRT.\]


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