JEE Main & Advanced Chemistry Structure of Atom / परमाणु संरचना Question Bank Self Evaluation Test - Structure of Atom

  • question_answer
    What is the angular velocity \[\left( \omega  \right)\] of an electron occupying second orbit of \[L{{i}^{2+}}\]ion?

    A) \[\frac{8{{\pi }^{3}}m{{e}^{4}}}{{{h}^{3}}}{{K}^{2}}\]  

    B) \[\frac{8{{\pi }^{3}}m{{e}^{4}}}{9{{h}^{3}}}{{K}^{2}}\]

    C) \[\frac{64}{9}\times \frac{{{\pi }^{3}}m{{e}^{4}}}{{{h}^{3}}}{{K}^{2}}\]

    D) \[\frac{9{{\pi }^{3}}m{{e}^{4}}}{{{h}^{3}}}{{K}^{2}}\]

    Correct Answer: D

    Solution :

    [d]  \[{{v}_{n}}={{r}_{n}}\omega \] where \[{{r}_{n}}=\frac{{{n}^{2}}{{h}^{2}}}{4{{\pi }^{2}}m{{e}^{2}}Z.K}\] and \[{{v}_{n}}=\frac{2\pi \cdot Z\cdot {{e}^{2}}\cdot K}{n\cdot h\cdot }\] \[\therefore =\frac{2\pi Z{{e}^{2}}\cdot K}{n\cdot h\cdot }=\frac{{{n}^{2}}{{h}^{2}}}{4{{\pi }^{2}}m{{e}^{2}}Z\cdot K}\times \omega ;\] \[\omega =\frac{8{{\pi }^{3}}m{{e}^{4}}\cdot {{Z}^{2}}\cdot {{K}^{2}}}{{{n}^{3}}\cdot {{h}^{3}}}\] \[=\frac{9{{\pi }^{3}}m{{e}^{4}}\cdot {{K}^{2}}}{{{h}^{3}}}(\therefore n=2and\,Z=3)\]


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