NEET Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Self Evaluation Test - The d-and f-Block Elements

  • question_answer
    The correct order of magnetic moments (spin only values in B.M.) among is (Atomic nos.: Mn = 25, Fe = 26, Co = 27)

    A) \[{{\left[ Fe{{\left( CN \right)}_{6}} \right]}^{4-}}>{{\left[ MnC{{l}_{4}} \right]}^{2}}^{-}>{{\left[ CoC{{l}_{4}} \right]}^{2-}}\]

    B) \[{{[MnC{{l}_{4}}]}^{2-}}>{{[Fe{{(CN)}_{6}}]}^{4-}}>{{[CoC{{l}_{4}}]}^{2-}}\]

    C) \[{{[MnC{{l}_{4}}]}^{2-}}>{{[Co{{(Cl)}_{4}}]}^{2-}}>{{[Fe{{(CN)}_{6}}]}^{4-}}\]

    D) \[{{[Fe{{(CN)}_{6}}]}^{4-}}>{{[Co{{(Cl)}_{4}}]}^{2-}}>{{[MnC{{l}_{4}}]}^{2-}}\] 

    Correct Answer: C

    Solution :

    [c] \[{{[Fe{{(CN)}_{6}}]}^{4-}}\] no of unpaired electron = 0 no of unpaired electron = 5 no of unpaired electron = 3 The greater the number of unpaired electrons, greater the magnitude of magnetic moment. Hence the correct order will be \[{{[MnC{{l}_{4}}]}^{2-}}>{{[CoC{{l}_{4}}]}^{2+}}>{{[Fe{{(CN)}_{6}}]}^{4-}}\]


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