JEE Main & Advanced Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II Question Bank Self Evaluation Test - The p-Block Elements (Group 13 and Group 14)

  • question_answer
    On adding ammonium hydroxide solution to \[A{{l}_{2}}{{(S{{O}_{4}})}_{3}}(aq)\]: 

    A) A precipitate is formed which does not dissolve in excess of ammonium hydroxide

    B) A precipitate is formed which dissolves in excess of ammonia solution

    C) No precipitate is formed

    D) None of these

    Correct Answer: A

    Solution :

    [a] \[A{{l}_{2}}{{\left( S{{O}_{4}} \right)}_{3}}+6N{{H}_{4}}OH\xrightarrow{{}}\] \[2Al{{\left( OH \right)}_{3}}+3{{\left( N{{H}_{4}} \right)}_{2}}S{{O}_{4}}\] \[Al{{\left( OH \right)}_{3}}+NaOH\xrightarrow{{}}\underset{Soluble\text{ }complex}{\mathop{N{{a}^{+}}{{\left[ Al{{\left( OH \right)}_{4}} \right]}^{-}}}}\,\] It is insoluble in \[N{{H}_{4}}OH.\]


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