12th Class Chemistry Sample Paper Chemistry Sample Test Paper-7

  • question_answer
      Explain the following with suitable example :                                                                                                      (Value Based) (a) Cationic detergent                                                                                                                                                                    1 (b) Anionic detergent                                                                                                                                                                    1 (c) Non-ionic detergents.                                                                                                                                                             1

    Answer:

                      (i) Cationic detergent: Cationic detergents are quaternary ammonium salts of acetates, chlorides, or bromides.                 These are called cationic detergents because the cationic part of these detergents contains a long hydrocarbon                 chain and a positive charge on the N atom.+ For example: cetyl tri methylammonium bromide. (ii) Anionic detergents: Anionic detergents sire of two types: 1.       Sodium alkyl sulphates: These detergents are sodium slats of long chain alcohols. They are prepared by first treating these alcohols with concentrated sulphuric acid and then with sodium hydroxide. Examples of these detergents include sodium lauryl sulphate and sodium stearylsulphate . 2.       Sodium alkylbenzenesulphonates : These detergents are sodium slats of longchain alkyl benzene sulphonic acids. They are prepared by Friedel - Craftsalkylation of benzene with long chain alkyl halides or alkenes. The obtained product is first treated with concentrated sulphuric acid and then with sodium hydroxide. Sodium 4-(1-dodecy) benzene sulphonate (SDS) is an example of anionic detergents.                                                                                1   (iii) Non-ionic detergents: Molecules of these detergents do not contain any inos. These detergents are esters of alcohols having high molecular mass. They are obtained by reacting polyethylene glycol and stearic acid.                                                                                                                        1


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