The correct order of increasing basic nature of the following bases is |
I.![]() |
II.![]() |
III. ![]() |
IV. ![]() |
A) \[II<V<I<III<IV\]
B) \[V<II<I<III<IV\]
C) \[II<V<I<IV<III\]
D) \[V<II<I<IV<III\]
Correct Answer: A
Solution :
[a] : \[-OC{{H}_{3}}\]is strongest electron releasing group (+M effect) which opposes most the dispersion of lone pair of electrons of nitrogen into the ring. Thus, \[-OC{{H}_{3}}\]being at para position imparts highest basicity. \[-N{{O}_{2}}\]being at meta position stabilises the electron pair of nitrogen only by -I effect. While \[-N{{O}_{2}}\]being present at para position due to -M effect and -I effect stabilises the lone pair of electrons of nitrogen most and imparts least basicity.You need to login to perform this action.
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