JEE Main & Advanced Sample Paper JEE Main - Mock Test - 29

  • question_answer
    Which of the following statements is not true?

    A) Diastereomers have different melting points and solubilities in a given solvent.

    B) Diastereomers have similar chemical properties.

    C) Diastereomers are optically active compounds with same or opposite sign of rotation.

    D) Diastereomers differ in adsorption.

    Correct Answer: C

    Solution :

    [c] (1) is true, (2) is true, and (4) is true. (Adsorption is a physical property. So it is different for diasteroemers.) (3) is not true. Diastereomers can be optically inactive, e.g., cis-2- butene and trans-2-butene are geometrical isomers and are diastereomers. Similarly, gauche and anti-forms are not optically active and are conformers and diastereomers.


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