JEE Main & Advanced Sample Paper JEE Main - Mock Test - 8

  • question_answer
    Select the rate law that corresponds to data shown for the following reaction \[A+B\xrightarrow{{}}\]products.
    Exp. [A] [B] Initial rate
    1 \[0.012\] \[0.035\] \[0.1\]
    2 \[0.024\] \[0.070\] \[0.8\]
    3 \[0.024\] \[0.035\] \[0.1\]
    4 \[0.012\] \[0.070\] \[0.8\]

    A) rate \[=k{{[B]}^{3}}\]       

    B) rate \[=k{{[B]}^{4}}\]

    C) rate \[=k[A]\,{{[B]}^{3}}\]   

    D) rate \[=k{{[A]}^{2}}\,{{[B]}^{2}}\]

    Correct Answer: A

    Solution :

    From data 1 and 3, it is clear that keeping [B] const, [A] is doubled, rate remains unaffected. Hence rate is independent of [A]. From 1 and 4, keeping [A] constant, [B] is doubled, rate become 8 times. Hence rate \[\propto {{[B]}^{3}}\]


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