JEE Main & Advanced Sample Paper JEE Main Sample Paper-18

  • question_answer
    The quantity of electricity needed to electrolyse completely 1 M solution of \[CuS{{O}_{4}},\,B{{i}_{2}}{{(S{{O}_{4}})}_{3}},\] \[AlC{{l}_{3}}\] and \[AgN{{O}_{3}}\] each will be

    A)  2F, 6F, 3F, and 1F, respectively

    B)  6F, 2F, 3F and 1F, respectively

    C)  2F, 6F, 1F and 3F, respectively

    D)  6F, 2F, 1F and 3F, respectively

    Correct Answer: A

    Solution :

     \[CuS{{O}_{4}}+2{{e}^{-}}\xrightarrow{{}}Cu+SO_{4}^{\,-}\] \[B{{i}_{2}}{{(S{{O}_{4}})}_{3}}+6{{e}^{-}}\xrightarrow{{}}2Bi+3SO_{4}^{-}\] \[AlC{{l}_{3}}+3{{e}^{-}}\xrightarrow{{}}Al+3C{{l}^{-}}\] \[AgN{{O}_{3}}+{{e}^{-}}\xrightarrow{{}}Ag+NO_{3}^{-}\] In 1 M\[CuS{{O}_{4}}\] solution, 1 M\[B{{i}_{2}}{{(S{{O}_{4}})}_{3}}\]solution, 1 M\[AlC{{l}_{3}}\] solution and 1 M\[AgN{{O}_{3}}\]solution, 2 mole electron, 6 mole electron, 3 mole electron and 1 mole electron are needed to deposit Cu, Bi, Al and Ag at the cathode, respectively. But one mole electron = 1 F electricity That's why number of Faraday required to deposit 1 M of each \[CuS{{O}_{4}},\] \[B{{i}_{2}}{{(S{{O}_{4}})}_{3}},\] and \[AgN{{O}_{3}}\] solution are 2F, 6F, 3P and F, respectively.


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