JEE Main & Advanced Sample Paper JEE Main Sample Paper-18

  • question_answer
    Dehydration of butan-2-ol with cone.\[{{H}_{2}}S{{O}_{4}}\]gives preferred product.

    A)  but-1-ene                         

    B)  but-2-ene

    C)  propene            

    D)  ethane

    Correct Answer: B

    Solution :

     \[C{{H}_{3}}-\overset{H}{\mathop{\overset{\mathbf{|}}{\mathop{CH}}\,}}\,-\overset{OH}{\mathop{\overset{\mathbf{|}}{\mathop{CH}}\,}}\,-C{{H}_{3}}\xrightarrow[\Delta ]{{{H}_{2}}S{{O}_{4}}}C{{H}_{3}}-CH=\] \[CH-C{{H}_{3}}(80%)+C{{H}_{3}}-C{{H}_{2}}-CH=C{{H}_{2}}(20%)\] This is in accordance with Saytzeff rule.


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