A) \[50\,ml.\]
B) \[100\,ml.\]
C) \[200\,ml.\]
D) None of these
Correct Answer: B
Solution :
Let V ml of \[RN{{H}_{3}}Cl\] added into \[RN{{H}_{2}}\]solution \[[RN{{H}_{3}}Cl]\]in resultant solution \[=\frac{0.2\times V}{100+V}\] \[[RN{{H}_{2}}]=\frac{100\times 0.1}{100+V};pOH=p{{K}_{b}}+\log \frac{[RNH_{3}^{+}]}{[RN{{H}_{2}}]}\] \[5.3=5+\log \left[ \frac{\left( \frac{0.2\times V}{100+V} \right)}{\frac{100\times 0.1}{100+V}} \right]\]\[\therefore \] \[2=\frac{0.2\times V}{10}\Rightarrow V=V=100ml.\]
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